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Impacts of Surface Reconstruction and Metal Dissolution on Ru<sub>1–<i>x</i></sub>Ti<sub><i>x</i></sub>O<sub>2</sub> Acidic Oxygen Evolution Electrocatalysts

Francisco Ospina‐Acevedo, José Fernando Godínez-Salomón, Zachary G. Naymik, Kevin C. Matthews, Jamie H. Warner, Christopher P. Rhodes, Perla B. Balbuena

2025The Journal of Physical Chemistry C16 citationsDOIOpen Access PDF

Abstract

surface. The experimentally observed changes in activity and surface structure after cycling are consistent with computational analysis, which shows how metal dissolution may alter the OER activation barriers. Combining experimental and computational insights, this work reveals the effects of metal dissolution on the surface atomic and electronic structure and OER activity and advances our comprehension of metal dissolution dynamics and surface reconstruction, which may have implications for other catalytic processes.

Topics & Concepts

DissolutionOxygen evolutionOxygenMetalMaterials scienceInorganic chemistryCrystallographyChemistryMetallurgyPhysical chemistryElectrochemistryElectrodeOrganic chemistryElectrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsAdvanced battery technologies research