Discovery of two new isomers of cyanoacenaphthylene (C <sub>12</sub> H <sub>7</sub> CN) in the Taurus molecular cloud 1 with the QUIJOTE line survey
J. Cernicharo, B. Tercero, N. Marcelino, J. A. López-Pérez, J. D. Gallego, F. Tercero, G. Esplugues, C. Cabezas, M. Agúndez, C. Limeres, Amanda L. Steber, Dolores Pérez, Cristóbal Pérez, Alberto Lesarri, P. de Vicente
Abstract
We report the discovery of the 3- and 4-cyano isomers of acenaphthylene (C 12 H 8 ) using the QUIJOTE line survey of the Taurus molecular cloud 1 (TMC-1). The frequency range of the line survey in the Q band (31.2–50.3 GHz) was complemented with data from a new receiver installed at the Yebes 40m radio telescope that covers the K and K a bands (18–32 GHz). The identification of 3-cyanoacenaphthylene was based on the detection of 135 individual lines that correspond to 194 rotational transitions. For 4-cyanoacenaphthylene, the lines are slightly weaker, but we identified 37 individual lines that correspond to 66 rotational transitions. As a first step for the identification, we compared the derived rotational constants with their expected theoretical values and obtained a match better than 0.2%. Finally, the new isomers were synthesized in our chemical laboratory and observed in our microwave spectroscopic facilities. The derived laboratory constants match those derived from TMC-1 data perfectly, which confirms our identifications. Lines in the K − K a band from the previously detected isomers 1- and 5-cyanoacenaphthylene are also reported. The derived column density for 3-cyanoacenaphthylene is (7.0 ± 0.7) × 10 11 cm −2 , and for the 4-cyano isomer, we derive a column density of (5.0 ± 0.6) × 10 11 cm −2 . The four possible isomers of cyanoacenaphthylene are finally found in TMC-1. Despite their high relative energies, they exhibit similar abundances (within a factor of ∼2).