Fabrication of Stable MIL-53(Al) for Excellent Removal of Rhodamine B
Xiaoyu Ma, Jiangyao Tan, Zuhao Li, Dongan Huang, Shan Xue, Yinqi Xu, Haisheng Tao
Abstract
Adsorptive purification of organic dyes in wastewater is significant to protect the water environment. Herein, MIL-53(Al) was successfully fabricated through a facile and versatile solvothermal strategy. The stability of MIL-53(Al) under high temperature, acid, base, and peroxide conditions was investigated. The porous MIL-53(Al) had high chemical stability, and the thermal stability reached up to 500 °C, which provided a good foundation for dye removal. MIL-53(Al) showed excellent adsorption performance. The maximum adsorption capacity of MIL-53(Al) for rhodamine B (RhB) can reach 1547 mg g–1 under 303 K, and the corresponding removal efficiency exceeded 90% at the equilibrium time (120 min). The Langmuir model and pseudo-second-order model can well fit RhB adsorption on MIL-53(Al). Thermodynamic study and activation energy values over the range of 298–323 K revealed that the adsorption of RhB was a spontaneous and endothermic physical process in nature. The batch experimental results, X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared (FTIR) spectroscopy analyses suggested that the hydrogen bonding and electrostatic interactions between the hydroxyl/carboxyl groups of MIL-53(Al) and RhB were the primary adsorption mechanisms. Besides, MIL-53(Al) had a higher selectivity to RhB than the coexisting ions in aqueous solution and a superior adsorption performance after five cycles.