Light-promoted copper-catalyzed cage C-arylation of <i>o</i>-carboranes: facile synthesis of 1-aryl-<i>o</i>-carboranes and <i>o</i>-carborane-fused cyclics
Hangcheng Ni, Zhenpin Lu, Zuowei Xie
Abstract
Light-promoted, copper catalyzed cage C–H arylation of o -carboranes with aryl halides has been achieved, leading to the facile synthesis of a variety of 1-aryl- o -carboranes and o -carborane-fused cyclics.
Topics & Concepts
ChemistryCarboraneArylCatalysisCopperCageHalideMedicinal chemistryPolymer chemistryCombinatorial chemistryOrganic chemistryAlkylMathematicsCombinatoricsBoron Compounds in ChemistryTraumatic Brain Injury and Neurovascular DisturbancesMedical Imaging Techniques and Applications