Concerted proton–electron transfer reactions of manganese–hydroxo and manganese–oxo complexes
Jaycee R. Mayfield, Elizabeth N. Grotemeyer, Timothy A. Jackson
Abstract
Studies of Mn<sup>III</sup>–hydroxo and Mn<sup>IV</sup>–oxo complexes that feature systematically perturbed ligand environments permit elucidation of structure–activity relationships that enhance our understanding of CPET processes in biological and synthetic systems.
Topics & Concepts
ManganeseProtonElectron transferChemistryElectronPhotochemistryInorganic chemistryOrganic chemistryPhysicsQuantum mechanicsMetal-Catalyzed Oxygenation MechanismsPhotosynthetic Processes and MechanismsPorphyrin and Phthalocyanine Chemistry