Engineering the geometric and electronic structure of Ru <i>via</i> Ru–TiO<sub>2</sub> interaction for enhanced selective hydrogenation
Qiang Zhou, Zijiang Zhao, Zihao Yao, Zhongzhe Wei, Songtao Huang, Fangjun Shao, Aiyuan Li, Jianguo Wang
Abstract
Ru/TiO 2 -Vo-250H with the structure of TiO 2 -Vo-partially encapsulated Ru nanoparticles, balances the active sites for H 2 dissociation and the adsorption sites for 6-chloroquinoline, achieving the selective hydrogenation even at room temperature.
Topics & Concepts
Dissociation (chemistry)RutheniumCatalysisAdsorptionNanoparticleChemistryChemical engineeringNanotechnologyPhotochemistryInorganic chemistryMaterials sciencePhysical chemistryOrganic chemistryEngineeringNanomaterials for catalytic reactionsAmmonia Synthesis and Nitrogen ReductionAsymmetric Hydrogenation and Catalysis