Palladium-catalyzed three-component 1,4-aminoarylation of [60]fullerene with aryl iodides and <i>N</i>-methoxysulfonamides, and further transformations
Yi‐Tan Su, Zheng‐Chun Yin, Guan‐Wu Wang
Abstract
The palladium-catalyzed three-component 1,4-aminoarylation of [60]fullerene afforded 1,4-(aryl)(sulfonamide)[60]fullerenes, of which the sulfonamide group could be replaced by a (hetero)aryl, malonate ester or allyl group in the presence of FeCl 3 .
Topics & Concepts
ChemistryArylPalladiumSulfonamideMalonateFullereneCatalysisMedicinal chemistryOrganic chemistryCombinatorial chemistryAlkylFullerene Chemistry and ApplicationsSynthesis and Properties of Aromatic CompoundsPorphyrin and Phthalocyanine Chemistry