Structural‐Deformation‐Energy‐Modulation Strategy in a Soft Porous Coordination Polymer with an Interpenetrated Framework
Yifan Gu, Jia‐Jia Zheng, Ken‐ichi Otake, Kunihisa Sugimoto, Nobuhiko Hosono, Shigeyoshi Sakaki, Fengting Li, Susumu Kitagawa
Abstract
Abstract To achieve unique molecular‐recognition patterns, a rational control of the flexibility of porous coordination polymers (PCPs) is highly sought, but it remains elusive. From a thermodynamic perspective, the competitive relationship between the structural deformation energy ( E def ) of soft PCPs and the guest interaction is key for selective a guest‐triggered structural‐transformation behavior. Therefore, it is vital to investigate and control E def to regulate this competition for flexibility control. Driven by these theoretical insights, we demonstrate an E def ‐modulation strategy via encoding inter‐framework hydrogen bonds into a soft PCP with an interpenetrated structure. As a proof of this concept, the enhanced E def of PCP enables a selective gate‐opening behavior toward CHCl 3 over CH 2 Cl 2 by changing the adsorption‐energy landscape of the compounds. This study provides a new direction for the design of functional soft porous materials.