Eutectic Electrolytes with Doubly‐Bound Water for High‐Stability Zinc Anodes
Dong Han, Tianjiang Sun, Ruochen Zhang, Weijia Zhang, Tao Ma, Haihui Du, Qiaoran Wang, Dan He, Shibing Zheng, Zhanliang Tao
Abstract
Abstract The aqueous zinc‐ion battery has the advantages of environmental friendliness, safety, and reliability, which is expected to be used for large‐scale energy storage. However, due to the high activity of water, the hydrogen evolution reaction (HER) easily occurs on the surface of the zinc anode during the charge–discharge process, which is accompanied by corrosion, by‐products, and dendrite formation. Herein, a new‐type eutectic electrolyte consisting of ZnCl 2 , tetramethylurea (TMU), and H 2 O with the optimal molar ratio of 1:3:1 (ZT‐1) is developed for the high‐stability zinc anodes. The H 2 O in this system is doubly bound through the coordination with Zn 2+ and the hydrogen bonding with TMU, thus leading to the greatly inhibited activity of H 2 O. In addition, the H 2 O and TMU are successively stripped during the desolvation process of ZnCl 2 (TMU)(H 2 O), followed by the deposition of [ZnCl 2 ] at the zinc interface. In this way, the tendency of HER, corrosion, dendrites, and by‐products induced by the decomposition of H 2 O molecules at the zinc interface is minimized, enabling a much more stable plating/stripping process of Zn 2+ . Consequently, the Zn//Zn symmetric cell can stably cycle for >2000 h, while the Zn//Cu half cell can stably cycle 800 times with an average Coulombic efficiency of 99.5%.