Litcius/Paper detail

N^N<i>vs.</i>N^E (E = S or Se) coordination behavior of imino-phosphanamidinate chalcogenide ligands towards aluminum alkyls: efficient hydroboration catalysis of nitriles, alkynes, and alkenes

Himadri Karmakar, Ravi Kumar, Jyoti Sharma, Jayanta Bag, Kuntal Pal, Tarun K. Panda, Vadapalli Chandrasekhar

2023Dalton Transactions13 citationsDOI

Abstract

Six aluminum complexes supported by imino-phosphanamidinate chalcogenide ligands are synthesized, structurally characterized and utilized as competent catalysts for hydroboration of nitriles, alkynes, and alkenes under mild and solvent-free conditions.

Topics & Concepts

ChemistryHydroborationCatalysisMedicinal chemistryChalcogenAlkylChalcogenideOrganic chemistrySynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryAsymmetric Hydrogenation and Catalysis