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Recovery from plasma etching-induced nitrogen vacancies in p-type gallium nitride using UV/O3 treatments

Geoffrey M. Foster, Andrew D. Koehler, Mona A. Ebrish, James C. Gallagher, Travis J. Anderson, Brenton A. Noesges, L. J. Brillson, Brendan Gunning, Karl D. Hobart, Francis J. Kub

2020Applied Physics Letters25 citationsDOIOpen Access PDF

Abstract

Plasma etching of p-type GaN creates n-type nitrogen vacancy (VN) defects at the etched surface, which can be detrimental to device performance. In mesa isolated diodes, etch damage on the sidewalls degrades the ideality factor and leakage current. A treatment was developed to recover both the ideality factor and leakage current, which uses UV/O3 treatment to oxidize the damaged layers followed by HF etching to remove them. The temperature dependent I–V measurement shows that the reverse leakage transport mechanism is dominated by Poole–Frenkel emission at room temperature through the etch-induced VN defect. Depth resolved cathodoluminescence confirms that the damage is limited to first several nanometers and is consistent with the VN defect.

Topics & Concepts

CathodoluminescenceMaterials scienceEtching (microfabrication)DiodePlasma etchingLeakage (economics)Gallium nitrideOptoelectronicsVacancy defectPlasmaNitrogenGalliumNanometreWide-bandgap semiconductorResistNitrideAnalytical Chemistry (journal)NanotechnologyChemistryComposite materialLayer (electronics)MetallurgyCrystallographyLuminescenceQuantum mechanicsEconomicsChromatographyMacroeconomicsOrganic chemistryPhysicsGaN-based semiconductor devices and materialsGa2O3 and related materialsZnO doping and properties
Recovery from plasma etching-induced nitrogen vacancies in p-type gallium nitride using UV/O3 treatments | Litcius