Multiple Interpenetrating Metal–Organic Frameworks with Channel-Size-Dependent Behavior for Selective Gossypol Detection and Perovskite Quantum Dot Encapsulation
Xin Jiang, Jian Zhang, Ruiqing Fan, Xuesong Zhou, Ke Zhu, Yulin Yang
Abstract
An interpenetrating structure endows metal–organic frameworks (MOFs) with many exciting applications, such as fluorescence detection and host–guest chemistry. Herein, two unique structure-interpenetrating In-MOFs (In-pdda-1 and In-pdda-2; H2pdda = 4,4′-(pyridine-2,5-diyl)dibenzoic acid) are constructed by different coordination configurations. The four-connected In3+ center shows a triangular-pyramidal configuration or a 2D rectangle, forming an unc topology for In-pdda-1 and a sql network for In-pdda-2, respectively. Two different interpenetrating modes created by linear rigid ligands and metal clusters are observed in the two MOFs (In-pdda-1, 8-fold interpenetrating mode; In-pdda-2, [2D + 2D] interpenetrating mode), which determine the channel-size-dependent properties in fluorescence applications. During the quantitative detection process of gossypol, the small rhombic channels divided by interpenetrating molecular planes of In-pdda-2 greatly limit the distance between the analyte and the probe, promoting electron transfer and energy transfer processes and thus resulting in a low detection limit (28.6 nM). In addition, the pore size effect of In-pdda-1 encouraged us to explore an in situ perovskite quantum dot encapsulation strategy to obtain a MAPbBr3@MOF material with tunable and stable luminescence properties. Both of the above channel-size-dependent fluorescence properties may provide inspiration for the structural design and specialized applications of MOF materials.