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Combining synchrotron radiation techniques for the analysis of gold coins from the Roman Empire

Ilaria Carlomagno, Patrik Zeller, Matteo Amati, Giuliana Aquilanti, E. Prenesti, Giovanna Marussi, Matteo Crosera, Gianpiero Adami

2022Scientific Reports15 citationsDOIOpen Access PDF

Abstract

Four gold coins minted in the V century have been studied with non-destructive synchrotron radiation techniques, namely X-Ray Fluorescence (XRF) and X-ray Absorption Near Edge Spectroscopy (XANES). XRF data analyzed coupling standard and statistical methods were used to distinguish the composition of the alloy constituting the coins from that of successive deposits processes. Our analysis presents a quantification of the trace elements present in the metallic alloy providing interesting details for historical insight. Furthermore, on the basis of the XRF maps, some regions of interest were selected for XANES at the K-edge of Fe. Our analysis of the Fe spectra points out two main phases which can be related to Fe oxides naturally present in soil. From the relative abundance of these oxides, information on the site where the coins were found can be obtained, providing additional information on their fate across the centuries.

Topics & Concepts

XANESSynchrotron radiationX-ray fluorescenceAlloySynchrotronMineralogyMaterials scienceGeologySpectral lineAnalytical Chemistry (journal)ChemistryPhysicsFluorescenceOpticsEnvironmental chemistryMetallurgyAstronomyX-ray Spectroscopy and Fluorescence AnalysisCultural Heritage Materials AnalysisLaser-induced spectroscopy and plasma
Combining synchrotron radiation techniques for the analysis of gold coins from the Roman Empire | Litcius