Developing a Novel Nanoscale Porphyrinic Metal–Organic Framework: A Bifunctional Platform with Sensitive Fluorescent Detection and Elimination of Nitenpyram in Agricultural Environment
Jintong Liu, Wei Xiong, Lin Yao Ye, Wen Sheng Zhang, Hong Yang
Abstract
Developing a rapid sensing platform with effective pesticide degradation capabilities integrated into a single structure and realistic application is an imminent challenge to ensure sustainable agriculture and food safety. Here, we described establishment of a bifunctional nanoscale porphyrinic metal–organic framework (MOF) probe serving as a sensor for detection of trace nitenpyram and as a photocatalyst to facilitate the pesticide degradation. Based on the signal turned “on–off”, the strong fluorescence of the probe was quenched by the target, leading to the sensing range from 0.05 to 10.0 μg mL–1 and a detection limit of 0.03 μg mL–1. Given the versatile design by which the porphyrin photosensitizers were isolated subtly in the MOF to avoid self-quenching, the probe was endowed with sustainable and efficient pesticide photodegradation activity with a degradation rate of ∼95% for nitenpyram. Our work represents powerful all-in-one MOF-derived materials jointly for sensing and degrading pesticide residues in agricultural soils and other pesticide-contaminated environments.