Tuning intramolecular electron transfer of cyanide bridged [Co<sub>2</sub>Fe<sub>2</sub>] squares through chemical modifications in solid and solution
Pei‐Ye You, Rong‐Jia Wei, Mo Xie, Guo‐Hong Ning, Hiroki Oshio
Abstract
We report three cyanide-bridged [Co 2 Fe 2 ] molecular squares by systematic ligand substitution and their tunable electron-transfer-coupled spin transition (ETCST) behaviors in solid and solution.
Topics & Concepts
CyanideIntramolecular forceElectron transferLigand (biochemistry)ChemistryCrystallographySolid solutionElectronMaterials scienceInorganic chemistryPhysical chemistryStereochemistryOrganic chemistryPhysicsQuantum mechanicsReceptorBiochemistryMagnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes