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Gas Permeability Test Protocol for Ion-Exchange Membranes

Eun Joo Park, Siddharth Komini Babu, Yu Seung Kim

2022Frontiers in Energy Research16 citationsDOIOpen Access PDF

Abstract

The membrane-based electrolysis of water is a growing topic of interest due to the advantages of employing membranes in hydrogen production efficiency and system safety over the traditional alkaline water electrolysis. Ion-exchange membranes with low gas permeability are highly desirable for stable and safe operation of membrane-based water-splitting technologies, hence gas permeability through ion-exchange membranes needs to be properly assessed with standardized methods. We addressed three methods to measure gas permeability of ion-exchange membranes, a pressure permeation cell, chronoamperometry microelectrodes, and in situ testing of the membrane electrode assembly, and provide a guideline for choosing the appropriate method for the targeted operating conditions of the water electrolyzers.

Topics & Concepts

MembraneChronoamperometryElectrolysisPermeability (electromagnetism)PermeationChemistryIon exchangeHydrogenChemical engineeringElectrolysis of waterMaterials scienceIonElectrodeElectrochemistryCyclic voltammetryEngineeringElectrolyteOrganic chemistryBiochemistryPhysical chemistryFuel Cells and Related MaterialsHybrid Renewable Energy SystemsElectrocatalysts for Energy Conversion
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