Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttle
Bryan H. R. Suryanto, Karolina Matuszek, Jaecheol Choi, Rebecca Y. Hodgetts, Hoang‐Long Du, Jacinta M. Bakker, Colin S. M. Kang, Pavel V. Cherepanov, Alexandr N. Simonov, Douglas R. MacFarlane
Abstract
Shuttling protons in ammonia synthesis An electrochemical route to ammonia could substantially lower the greenhouse gas emissions associated with the current thermal Haber-Bosch process. One relatively promising option under study involves reductive formation of lithium nitride, which can be protonated to ammonia. However, the ethanol used to date as a local proton source in these studies may degrade under the reaction conditions. Suryanto et al. report the use of a tetraalkyl phosphonium salt in place of ethanol (see the Perspective by Westhead et al. ). This cation can stably undergo deprotonation–reprotonation cycles and, as an added benefit, it enhances the ionic conductivity of the medium. Science , abg2371, this issue p. 1187 ; see also abi8329, p. 1149