Litcius/Paper detail

Engineering of zeolite BEA crystal size and morphology <i>via</i> seed-directed steam assisted conversion

T. O. Bok, E. P. Andriako, E. E. Knyazeva, І. І. Іванова

2020RSC Advances49 citationsDOIOpen Access PDF

Abstract

= 250) dissolve into tiny fragments, which serve as individual nuclei leading to formation of tiny isolated nanocrystallites aggregated into small hierarchical aggregates with high intercrystalline mesoporosity. The decrease of particle size and formation of intercrystalline mesoporosity in hierarchical aggregates improves the accessibility of acidic sites and facilitates the diffusion of reaction products, which leads to the significant improvement of catalytic activity and reduces the deactivation resulting in higher stability with time on stream in cumene synthesis from benzene and propylene.

Topics & Concepts

Chemical engineeringZeoliteDissolutionCatalysisParticle sizeMaterials scienceCrystal (programming language)ChemistryOrganic chemistryProgramming languageEngineeringComputer scienceZeolite Catalysis and SynthesisCatalysis and Oxidation ReactionsMesoporous Materials and Catalysis