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Porous organic polymers for electrocatalysis

Dong-Hui Yang, You Tao, Xuesong Ding, Bao-Hang Han

2022Chemical Society Reviews370 citationsDOI

Abstract

reduction reaction, nitrate/nitrite reduction reaction, nitrobenzene reduction reaction, hydrogen oxidation reaction, and benzyl alcohol oxidation reaction. Herein, we present a systematic overview of recent advances in the applications of POPs in these electrocatalytic reactions. The synthesis strategies, specific active sites, and catalytic mechanisms of POPs are summarized in this review. The fundamental principles of some electrocatalytic reactions are also concluded. We further discuss the current challenges of and perspectives on POPs for electrocatalytic applications. Meanwhile, the possible future directions are highlighted to afford guidelines for the development of efficient POP electrocatalysts.

Topics & Concepts

ElectrocatalystNitrobenzenePorosityPolymerCatalysisMaterials scienceNanotechnologyCovalent bondOxygen reductionReduction (mathematics)HydrogenChemistryOxygen reduction reactionChemical engineeringOxygen evolutionBenzyl alcoholRedoxElectrolysis of waterOrganic polymerSpecific surface areaOrganic synthesisPorous mediumOxygenCombinatorial chemistryAlcohol oxidationCovalent Organic Framework ApplicationsElectrocatalysts for Energy ConversionConducting polymers and applications
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