Visible-Light-Mediated (<i>sp</i><sup>3</sup>)Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
Sourav Roy, Indranil Chatterjee
Abstract
-bromosuccinamide-tetrahydrofuran electron donor-acceptor complex served as an initiator to functionalize both α-diazoketones and dialkyl azodicarboxylates. This developed methodology gives an alternative and milder way to construct the C-N bond and can be explored for the formation of C-C bond to perform arylation and allylation reactions.
Topics & Concepts
AminationTetrahydrofuranAcceptorElectron acceptorChemistryElectron donorSurface modificationEtherCombinatorial chemistryPolymer chemistryPhotochemistryOrganic chemistryCatalysisCondensed matter physicsPhysical chemistrySolventPhysicsCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsRadical Photochemical Reactions