All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters
Jinhua Liu, Li‐Dan Lin, Guoqiang Wang, Lingyun Li, Yan‐Qiong Sun, Xin‐Xiong Li, Shou‐Tian Zheng
Abstract
A series of all-inorganic POM-based open frameworks based on gigantic multilayer Ln@W<sub>8</sub>@Ln<sub>8</sub>@(SiW<sub>12</sub>)<sub>6</sub> (Ln = La, Pr and Nd) clusters have been fabricated and structurally characterized for the first time.
Topics & Concepts
Shell (structure)ChemistryMaterials scienceComposite materialMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications