Constrained Geometry <i>ansa</i>‐Half‐Sandwich Complexes of Magnesium – Versatile <i>s</i>‐Block Catalysts
Lisa Wirtz, Kinza Yasmin Ghulam, Bernd Morgenstern, André Schäfer
Abstract
Abstract The synthesis, characterization and catalytic application of a series of constrained geometry ansa ‐half‐sandwich complexes of magnesium is reported. These versatile s ‐block catalysts were applied in different dehydrocoupling and hydroelementation reactions, demonstrating a broad applicability with particularly remarkable performance in dehydrocoupling reactions.
Topics & Concepts
CatalysisMagnesiumBlock (permutation group theory)Characterization (materials science)Materials scienceChemistryNanotechnologyOrganic chemistryGeometryMathematicsMetallurgyOrganometallic Complex Synthesis and CatalysisCoordination Chemistry and OrganometallicsSynthesis and characterization of novel inorganic/organometallic compounds