Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers
Yue Pang, Markus Leutzsch, Nils Nöthling, Felix Katzenburg, Josep Cornellà
Abstract
)-H bond while regenerating the propagating Phebox-Bi(I). This protocol represents a distinct catalytic example where a main-group center performs three elementary organometallic steps in a low-valent redox manifold.
Topics & Concepts
ChemistryReductive eliminationOxidative additionTrifluoromethanesulfonateLigand (biochemistry)Catalytic cycleMetathesisCatalysisMedicinal chemistryCationic polymerizationSalt metathesis reactionRedoxHydrideCombinatorial chemistryPhotochemistryOrganic chemistryMetalPolymerizationPolymerBiochemistryReceptorCarbon dioxide utilization in catalysisFluorine in Organic ChemistryOrganoboron and organosilicon chemistry