Redox mediators accelerate electrochemically-driven solubility cycling of molecular transition metal complexes
Katherine J. Lee, Kunal M. Lodaya, Cole T. Gruninger, Eric S. Rountree, Jillian L. Dempsey
Abstract
. Finally, mathematical models are developed that describe the current-potential response for a generic EC' mechanism involving a homogeneous catalyst and surface-adsorbed substrate. This novel strategy has the potential to enable reversible redox chemistry for heterogeneous, molecular deposits that are adsorbed on the electrode or suspended as nanoparticles in solution.
Topics & Concepts
RedoxSolubilityHomogeneousTransition metalElectrochemistryChemistryMetalCyclingCombinatorial chemistryMaterials scienceElectrodeChemical engineeringInorganic chemistryOrganic chemistryCatalysisPhysical chemistryHistoryPhysicsArchaeologyThermodynamicsEngineeringAdvanced battery technologies researchElectrochemical Analysis and ApplicationsCO2 Reduction Techniques and Catalysts