Reactivity of [Pt(P<sup><i>t</i></sup>Bu<sub>3</sub>)<sub>2</sub>] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
Nereida Hidalgo, Carlos Romero‐Pérez, Celia Maya, Israel Fernández, Jesús Campos
Abstract
pairs (X = Cl, Br, I, and OTf) toward water and dihydrogen, which can be understood in terms of bimetallic frustration.
Topics & Concepts
ChemistryNegishi couplingZincBimetallic stripReactivity (psychology)ElectrophileSteric effectsAdductTransition metalCleavage (geology)Medicinal chemistryMetalStereochemistryOrganic chemistryCatalysisFracture (geology)PathologyAlternative medicineMedicineEngineeringGeotechnical engineeringOrganoboron and organosilicon chemistryCoordination Chemistry and OrganometallicsCatalytic Cross-Coupling Reactions