Dirhodium: carbene transformations and beyond
Wu Rui, Dong Zhu, Shifa Zhu
Abstract
Dirhodium-catalyzed transformations, not limited to carbene and nitrene transfer reactions, are reviewed, including cycloisomerization, hetero-Diels–Alder (HDA) reactions, ene reactions, arylation, radical oxidation reactions and C–H activation, etc .
Topics & Concepts
ChemistryNitreneCarbeneCycloisomerizationCatalysisPhotochemistryMedicinal chemistryOrganic chemistryCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis