An atropisomeric M<sub>2</sub>L<sub>4</sub>cage mixture displaying guest-induced convergence and strong guest emission in water
Takahiro Tsutsui, Lorenzo Catti, Kenji Yoza, Michito Yoshizawa
Abstract
A complex mixture of atropisomeric M<sub>2</sub>L<sub>4</sub>cages is shown to undergo perfect convergence to a single isomer upon encapsulation of spherical C<sub>60</sub>in water. Moreover, the cage mixture displays very strong guest emission upon encapsulation of a BODIPY dye.
Topics & Concepts
CageChemistryBODIPYEncapsulation (networking)PhotochemistryFluorescenceComputer sciencePhysicsCombinatoricsOpticsMathematicsComputer networkSupramolecular Chemistry and ComplexesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials