A polyoxometalate-encapsulated nanocage cluster organic framework built from {Cu<sub>4</sub>P<sub>2</sub>} units and its efficient bifunctional electrochemical performance
Shaobin Li, Xiaoguo Tan, Ming Yue, Li Zhang, Dong‐Feng Chai, Wendi Wang, Hong Pan, Linlin Fan, Chunyan Zhao
Abstract
The first polyoxometalate (POM)-encapsulated twenty-four-nucleus organophosphorus-copper nanocage cluster organic framework has been constructed. Here, the phosphomolybdate POMs were incorporated into an octahedral nanocage cluster organic framework, and the resulting material exhibited highly efficient bifunctional electrochemical performance. The crystalline material showed a high specific capacitance of 366.3 F g-1 at a current density of 3 A g-1.
Topics & Concepts
NanocagesPolyoxometalateBifunctionalCluster (spacecraft)ElectrochemistryOctahedronMaterials scienceCapacitanceCopperChemistryNanotechnologyChemical engineeringCrystallographyElectrodePhysical chemistryOrganic chemistryCrystal structureCatalysisMetallurgyComputer scienceProgramming languageEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications