Photocatalyzed cascade hydrogen atom transfer for the construction of α-CF <sub>3</sub> -1,4-diketones
Xiao-Ya Yuan, Jing-Fei Zheng, Xinyu Ma, Xianqiang Huang, Qi‐Yan Lv, Kai Sun, Xiaolan Chen, Lingbo Qu, Bing Yu
Abstract
A TBADT-photocatalyzed cascade hydrogen atom transfer procedure was established for the synthesis of α-CF 3 -1,4-diketones from aldehydes and 2-bromo-3,3,3-trifluoro-1-propenes.
Topics & Concepts
ChemistryCascadeHydrogen atomAtom (system on chip)PhotochemistryCombinatorial chemistryOrganic chemistryChromatographyEmbedded systemComputer scienceAlkylFluorine in Organic ChemistryInorganic Fluorides and Related CompoundsCarbon dioxide utilization in catalysis