Supramolecular Tessellations via Pillar[<i>n</i>]arenes-Based Exo–Wall Interactions
Ming Li, Bin Hua, Haozhong Liang, Jiyong Liu, Li Shao, Feihe Huang
Abstract
Supramolecular tessellation is a newly emerging and promising area in supramolecular chemistry because of its unique structural aesthetics and potential applications. Herein, we investigate the “exo–wall” interactions of pillar[n]arenes and prepare fantastic hexagonal supramolecular tessellations based on perethylated pillar[6]arenes (EtP6) with electron-deficient molecules 1,5-difluoro-2,4-dinitrobenzene (DFN) and tetrafluoro-1,4-benzoquinone (TFB). The crystal structures clearly confirm that EtP6 can form highly ordered hexagonal 2D tiling patterns with DFN/TFB as linkers through cocrystallization. Moreover, the self-assembled packing arrangements in the ultimate cocrystal superstructures can be adjusted under different crystallization conditions. This work not only explores the rare exo–wall interactions based on pillar[n]arenes but also reports the fabrication of supramolecular tessellations based on pillararenes for the first time, showing a new perspective in supramolecular chemistry.