The mechanochemical Scholl reaction as a versatile synthesis tool for the solvent-free generation of microporous polymers
Annika Krusenbaum, Sven Grätz, Sarah Bimmermann, Stefanie Hutsch, Lars Borchardt
Abstract
by liquid assisted grinding. Within this study we illuminate the origin of porosity by investigating the impact of various milling parameters and milling materials, temperature and pressure, and different liquids for LAG as well as post polymer milling. Finally we expand the procedure to different monomers and mills, to present the mechanochemical Scholl reaction as a versatile synthesis tool for porous polymers.
Topics & Concepts
Microporous materialPolymerizationPolymerBall millPolymer chemistryMechanochemistrySolventMaterials scienceChemical engineeringChemistryPolymer scienceOrganic chemistryNanotechnologyComposite materialEngineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials