3D printable, thermo-responsive, self-healing, graphene oxide containing self-assembled hydrogels formed from block copolymer wormlike micelles
Qi Yue, Zhidong Luo, Xueyuan Li, Lee A. Fielding
Abstract
polymerisation and containing 2% w/w GO based on copolymer. This gel strength represents a fifteen-fold increase over the same copolymer gel without the addition of GO. The nanocomposite gels were found to recover efficiently after the application of high shear, with up to 98% healing efficiency within seconds. These gels are also 3D printable, self-healing, adhesive and temperature responsive on cooling and re-heating. The observed properties were both GO and copolymer concentration dependent, and tensile testing demonstrated that the nanocomposite gels had higher moduli, elongation at break and toughness than gels prepared without GO.
Topics & Concepts
CopolymerSelf-healing hydrogelsSelf-healingMicelleMaterials scienceGrapheneOxideSelf-assemblyRaftPolymer chemistryNanocompositeAdhesivePolymerizationChemical engineeringNanotechnologyPolymerComposite materialChemistryAqueous solutionOrganic chemistryLayer (electronics)PathologyMedicineAlternative medicineEngineeringMetallurgyAdvanced Polymer Synthesis and CharacterizationHydrogels: synthesis, properties, applications