Sequential enhancement of proton conductivity by aliovalent cadmium substitution and post-synthetic esterolysis in a carboxylate-functionalized indium framework with dimethylaminium templates
Hui Gao, Yingxia Wang, Yanbin He, Xian‐Ming Zhang
Abstract
A sequential improving strategy of aliovalent Cd( ii ) substitution and post-synthetic ligand esterolysis has been proposed and implemented on a In( iii )-MOF. The modified framework Cd-BQ-COOH exhibits 300-fold enhanced value of proton conductivitiy.
Topics & Concepts
TemplateIndiumConductivityCarboxylateLigand (biochemistry)Substitution (logic)ProtonMaterials scienceChemistryCombinatorial chemistryNanotechnologyStereochemistryPhysical chemistryComputer scienceOptoelectronicsPhysicsReceptorBiochemistryQuantum mechanicsProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsFuel Cells and Related MaterialsAdvanced battery technologies research