Triazaphosphaadamantane-functionalized terpyridine metal complexes: cyclohexane oxidation in homogeneous and carbon-supported catalysis
Ivy L. Librando, Anup Paul, Abdallah G. Mahmoud, Atash V. Gurbanov, Sónia A. C. Carabineiro, M. Fátima C. Guedes da Silva, Carlos F. G. C. Geraldes, Armando J. L. Pombeiro
Abstract
A metal complex bearing 1,3,5-triaza-7-phosphaadamantane and terpyridine scaffolds as a single polydentate ligand was used as a recyclable catalyst for synthesizing the nylon precursor, KA oil.
Topics & Concepts
TerpyridineCyclohexaneHomogeneousCatalysisMetalHomogeneous catalysisChemistryCarbon fibersPolymer chemistryCombinatorial chemistryOrganic chemistryMaterials scienceComposite materialPhysicsComposite numberThermodynamicsOrganometallic Complex Synthesis and CatalysisMetal-Catalyzed Oxygenation MechanismsSynthetic Organic Chemistry Methods