Zinc acetate-promoted blocking of the ATRA process with alkyl halides enabling photochemical alkylamination of olefins
Apurba Samanta, Shyamal Pramanik, Subhashis Mondal, Soumitra Maity
Abstract
. A range of carbon-centered radicals (α-alkylcarbonyl, benzyl, cyanomethyl) are effectively participating in this strategy giving rise to versatile carboamination products with high synthetic value.
Topics & Concepts
ChemistryAlkylHalideNitrileRadicalPhotochemistryPhotoredox catalysisZincSolventBlocking (statistics)Organic chemistryCatalysisCombinatorial chemistryPhotocatalysisMathematicsStatisticsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions