A designed second-sphere hydrogen-bond interaction that critically influences the O–O bond activation for heterolytic cleavage in ferric iron–porphyrin complexes
Sarmistha Bhunia, Atanu Rana, Somdatta Ghosh Dey, Anabella Ivancich, Abhishek Dey
Abstract
sphere hydrogen bonding interaction can play a critical role in O-O bond heterolysis.
Topics & Concepts
HeterolysisPorphyrinChemistryFerricBond cleavageCleavage (geology)Hydrogen bondPhotochemistryCatalysisOrganic chemistryMoleculeMaterials scienceFracture (geology)Composite materialPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsHemoglobin structure and function