Iodonium complexes of the tertiary amines quinuclidine and 1-ethylpiperidine
Jas S. Ward, Antonio Frontera, Kari Rissanen
Abstract
Iodonium complexes incorporating tertiary amines have been synthesised to study and explore why such species comprised of alkyl amines are relatively rare. The complexes were characterised in solution (1H and 15N NMR spectroscopy) and the solid state (SCXRD), and analysed computationally.
Topics & Concepts
QuinuclidineTertiary careTertiary amineChemistryMedicinal chemistryStereochemistryOrganic chemistryMedicineFamily medicineCrystallography and molecular interactionsCoordination Chemistry and OrganometallicsChemical Reaction Mechanisms