Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
Maryam Neysi, Dawood Elhamifar
Abstract
Abstract A novel magnetic ionic liquid based periodic mesoporous organosilica supported palladium (Fe 3 O 4 @SiO 2 @IL-PMO/Pd) nanocomposite is synthesized, characterized and its catalytic performance is investigated in the Heck reaction. The Fe 3 O 4 @SiO 2 @IL-PMO/Pd nanocatalyst was characterized using FT-IR, PXRD, SEM, TEM, VSM, TG, nitrogen-sorption and EDX analyses. This nanocomposite was effectively employed as catalyst in the Heck reaction to give corresponding arylalkenes in high yield. The recovery test was performed to study the catalyst stability and durability under applied conditions.
Topics & Concepts
NanocompositeCatalysisMaterials scienceSorptionMesoporous materialIonic liquidPalladiumChemical engineeringYield (engineering)Nuclear chemistryOrganic chemistryChemistryNanotechnologyComposite materialAdsorptionEngineeringNanomaterials for catalytic reactionsMesoporous Materials and CatalysisCatalytic Cross-Coupling Reactions