SrAl<sub>2</sub>O<sub>4</sub> crystallite embedded inorganic medium with super-long persistent luminescence, thermoluminescence, and photostimulable luminescence for smart optical information storage
Panpan Li, Youjie Hua, Renguang Ye, Muzhi Cai, Shiqing Xu, Junjie Zhang
Abstract
As a leader of long persistent luminescence (LPL) materials, the optical properties of aluminate phosphor have remained unsurpassed for many years. As a powder material, its practical application will always be limited to the field of security signs. In this paper, the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="m1"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrAl</mml:mi> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">O</mml:mi> <mml:mn>4</mml:mn> </mml:msub> <mml:mo>:</mml:mo> <mml:msup> <mml:mrow> <mml:mi>Eu</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> , <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="m2"> <mml:mrow> <mml:msup> <mml:mrow> <mml:mi>Dy</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> inorganic solid material with comparable LPL properties to powder materials was obtained. The crystallization mechanism and crystallite micro-morphology of inorganic glass materials have been studied, and a new opinion is put forward that the large-size <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="m3"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrAl</mml:mi> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">O</mml:mi> <mml:mn>4</mml:mn> </mml:msub> </mml:mrow> </mml:math> crystallites in the glass matrix are stacked by rod-shaped crystals arranged in a regular direction. In addition, the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="m4"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrAl</mml:mi> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">O</mml:mi> <mml:mn>4</mml:mn> </mml:msub> <mml:mo>:</mml:mo> <mml:msup> <mml:mrow> <mml:mi>Eu</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> , <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" id="m5"> <mml:mrow> <mml:msup> <mml:mrow> <mml:mi>Dy</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> glass obtained cannot only collect high-energy photons but also is sensitive to low-energy sunlight. The results show that the material exhibits superior performance in LPL, thermoluminescence, and photostimulable luminescence. Based on this property, a new application of this material in the field of information storage was explored. This paper has a certain reference value for the development and application of aluminate LPL materials in the field of smart optical information storage.