One-Dimensional Highly-Confined CsPbBr<sub>3</sub> Nanorods with Enhanced Stability: Synthesis and Spectroscopy
Hua Zhu, Tara Šverko, Juanye Zhang, David B. Berkinsky, Weiwei Sun, Chantalle J. Krajewska, Moungi G. Bawendi
Abstract
One-dimensional (1D) colloidal lead halide perovskites (LHPs) have potential as quantum emitters. Their study, however, has been hampered by their previous instability, leaving a gap in our understanding of structure–property relationships in colloidal LHPs with anisotropic shapes. Here, we synthesize stable, highly-confined 1D CsPbBr3 nanorods (NRs) and demonstrate their structural details and photoluminescence (PL) properties at both the ensemble and single particle levels. Using amino-terminated copolymers, we are able to stabilize and characterize 1D CsPbBr3 NRs utilizing transmission electron microscopy (TEM) and small angle scattering (SAS). Scanning transmission electron microscopy reveals that these NRs possess structural defects, including twists and inhomogeneity. Solution-phase photon correlation spectroscopy shows low biexciton-to-exciton quantum yield ratios (QYBX/QYX) and broad spectral line widths dominated by homogeneous broadening.