Modified Graphite Paper Based Miniaturized Electrochemically Optimized Hydrazine Sensing Platform
Jaligam Murali Mohan, Khairunnisa Amreen, Arshad Javed, Satish Kumar Dubey, Sanket Goel
Abstract
In this work, a miniaturized platform for electrochemical detection of hydrazine, has been developed using droplet paper based three electrode system. Copper oxide cluster (CuO) immobilized on the surface of graphite sheet (Grp@CuO) is used as a working electrode. The developed Grp@CuO showed a surface-confined delayed redox response at an electrode potential (E 1/2 ) −0.24 V vs Ag/AgCl in pH 7 phosphate buffer solution (PBS). The physicochemical characterization of the Grp@CuO revealed the electro deposition of CuO cluster on the surface of graphite sheet. Grp@CuO displayed selective electro-catalytic activity towards the detection of hydrazine in pH 7.0 PBS. A systematic linear increase in the oxidation current is observed in the range of 1 μ M to 7 μ M at an applied potential of −0.6 to 0.2 V vs Ag/AgCl with an excellent current sensitivity, lower detection limit (0.3482 μ M). The fabricated miniaturized droplet-based sensor showed zero interference from other chemicals. Therefore, it is a viable option to be used in detection of hydrazine in real samples. Finally, the prepared platform was harnessed to real water samples for hydrazine detection.