Electron‐Extraction Engineering Induced 1T’’‐1T’ Phase Transition of Re<sub>0.75</sub>V<sub>0.25</sub>Se<sub>2</sub> for Ultrafast Sodium Ion Storage
Yuqiang Fang, Ximeng Lv, Zhuoran Lv, Yang Wang, Gengfeng Zheng, Fuqiang Huang
Abstract
Abstract Inducing new phases of transition metal dichalcogenides by controlling the d‐electron‐count has attracted much interest due to their novel structures and physicochemical properties. 1T’’ ReSe 2 is a promising candidate for sodium storage, but the low electronic conductivity and limited active sites hinder its electrochemical capacity. Herein, new‐phase 1T’ Re 0.75 V 0.25 Se 2 crystals (P 2/m ) with zig‐zag chains are successfully synthesized. The 1T’’‐1T’ phase transition results from the electronic reorganization of 5d orbitals via electron extraction after V‐atom doping. The electrical conductivity of 1T’ Re 0.75 V 0.25 Se 2 is 2.7 × 10 5 times higher than that of 1T’’ ReSe 2 . Moreover, density functional theory (DFT) calculations reveal that 1T’ Re 0.75 V 0.25 Se 2 has a larger interlayer spacing, lower bonding energy, and migration energy barrier for Na + ions than 1T’’ ReSe 2 . As a result, 1T’ Re 0.75 V 0.25 Se 2 electrode shows an excellent rate capability of 203 mAh g −1 at 50 C with no capacity fading over 5000 cycles for sodium storage, which is superior to most reported sodium‐ion anode materials. This 1T’ Re 0.75 V 0.25 Se 2 provides a new platform for various applications such as electronics, catalysis, and energy storage.