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Photocatalytic access to aromatic keto sulfonyl fluorides from vinyl fluorosulfates

Jianchao Cui, Sen Ke, Jia Zhao, Shufeng Wu, Wencheng Luo, Shinuo Xu, Xiaolong Su, Yi Li

2022Organic Chemistry Frontiers22 citationsDOI

Abstract

A photocatalytic transformation of vinyl fluorosulfates to aromatic β-keto sulfonyl fluorides is developed using 1 mol% of Ir catalyst irradiated by 3 W blue LEDs. This methodology provides an efficient and readily scalable approach to aromatic β-keto sulfonyl fluorides.

Topics & Concepts

SulfonylChemistryPhotocatalysisCatalysisOrganic chemistryCombinatorial chemistryAlkylSulfur-Based Synthesis TechniquesFluorine in Organic ChemistryRadical Photochemical Reactions