Litcius/Paper detail

Ru<sup>II</sup>complexes of 1,2,3-triazole appended tertiary phosphines, [P(Ph){(<i>o</i>-C<sub>6</sub>H<sub>4</sub>)(1,2,3-N<sub>3</sub>C(Ph)CH}<sub>2</sub>] and [P(Ph){<i>o</i>-C<sub>6</sub>H<sub>4</sub>(CCH)-(1,2,3-N<sub>3</sub>-Ph)}<sub>2</sub>]: highly active catalysts for transfer hydrogenation of carbonyl/nitro compounds and for α-alkylation of ketones

Pavan K. Namdeo, Sonu Sheokand, Basvaraj S. Kote, Latchupatula Radhakrishna, Harish S. Kunchur, Prateek Saini, Srinivasan Ramakrishnan, Maravanji S. Balakrishna

2022Dalton Transactions17 citationsDOI

Abstract

Ruthenium( ii ) complexes of two new triazole-appended NPN tridentate ligands and their catalytic studies are described.

Topics & Concepts

ChemistryCatalysisHydrideCationic polymerizationTransfer hydrogenationMedicinal chemistryNitroAlkoxideAlkylationMolar ratioDensity functional theoryCatalytic cycle1,2,4-TriazoleStereochemistryRutheniumMetalOrganic chemistryComputational chemistryAlkylAsymmetric Hydrogenation and CatalysisNanomaterials for catalytic reactionsCatalytic Cross-Coupling Reactions
Ru<sup>II</sup>complexes of 1,2,3-triazole appended tertiary phosphines, [P(Ph){(<i>o</i>-C<sub>6</sub>H<sub>4</sub>)(1,2,3-N<sub>3</sub>C(Ph)CH}<sub>2</sub>] and [P(Ph){<i>o</i>-C<sub>6</sub>H<sub>4</sub>(CCH)-(1,2,3-N<sub>3</sub>-Ph)}<sub>2</sub>]: highly active catalysts for transfer hydrogenation of carbonyl/nitro compounds and for α-alkylation of ketones | Litcius