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Regulation of surface oxygen activity in Li-rich layered cathodes using band alignment of vanadium phosphate surface coatings

T.R. Jenkins, José A. Alarco, Bruce C. C. Cowie, Ian D.R. Mackinnon

2022Journal of Materials Chemistry A18 citationsDOI

Abstract

Interfacial electronic band alignment between alkali vanadium( iii ) phosphate (Na 3 V 2 (PO 4 ) 3 , Li 3 V 2 (PO 4 ) 3 ) coatings regulate oxygen redox activity and enhance electrochemical performance in prototypical Li-rich layered oxide, Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 .

Topics & Concepts

VanadiumVanadium oxideElectrochemistryPhosphateAlkali metalCathodeOxygenOxideInorganic chemistryMaterials scienceRedoxChemistryElectrodeMetallurgyPhysical chemistryOrganic chemistryAdvancements in Battery MaterialsTransition Metal Oxide NanomaterialsSupercapacitor Materials and Fabrication
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