An artificial enzyme of a polyoxometalate-supported cobalt complex for the oxidation of isochromans to isochromanones by activating O<sub>2</sub>
Xiangyu Ren, Hongrui Tian, Baokuan Chen, Lingling Dai, Yanfeng Bi, Guo‐Ping Yang
Abstract
An artificial enzyme of a polyoxometalate-supported cobalt complex was synthesized in a decagram scale, which can activate O 2 for the oxidation of isochromans to isochromanones with high yields under mild conditions and without any additives.
Topics & Concepts
PolyoxometalateCobaltActive centerMetalChemistryCenter (category theory)Active siteEnzymeCoordination complexCombinatorial chemistryNanotechnologyMaterials scienceInorganic chemistryOrganic chemistryCrystallographyCatalysisMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry ReactionsVanadium and Halogenation Chemistry