Litcius/Paper detail

Coupled mixed-potential and thermal-hydraulics model for long-term corrosion of copper canisters in deep geological repository

Nakkyu Chae, Samuel Park, Seungjin Seo, Richard I. Foster, Heejae Ju, Sungyeol Choi

2023npj Materials Degradation19 citationsDOIOpen Access PDF

Abstract

Abstract Canister performance is a major issue for constructing reliable deep geological repositories for storing spent nuclear fuels, and corrosion resistance is main the factor determining canister durability. We developed a 2-D multiphysics model, which can predict both the corrosion rate and potential, for simulating copper canister corrosion in deep geological repositories. We found that canisters corroded through the long-cell action in a deep geological repository, the corrosion was quite limited, and the overall canister durability was around 1.7 million years. Our results demonstrated that copper exhibits sufficient corrosion resistance and that long-cell action-based corrosion cannot severely damage copper canisters.

Topics & Concepts

CorrosionSpent nuclear fuelCopperDurabilityRadioactive wasteMetallurgyMultiphysicsEnvironmental scienceMaterials scienceWaste managementEngineeringComposite materialFinite element methodStructural engineeringCorrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsEnhanced Oil Recovery Techniques