Litcius/Paper detail

Preparation and Characterization of a Bentonite-Based Hybrid Gel for Coal Spontaneous Combustion Prevention

Xiaoxing Zhong, Heda Jian, Guolan Dou, Jie Liu, Hanyue Tan

2022ACS Omega16 citationsDOIOpen Access PDF

Abstract

, lignocellulose, and XG into a bentonite suspension, and the resulting gel was characterized. The results showed that no cracking and powdering were found on the surface of the hybrid gel due to the formation of the cross-linked network in the bentonite, and a wide mesopore size distribution and good thermal stability were observed. The hybrid gel also exhibits a wide range of water adsorption ratios, excellent water retention, adjustable gelation times, shear thinning characteristics, and improved compressive strength (the yield stress reaches up to 13 MPa). Based on these characterizations, the mechanism of hybrid gel formation is proposed. The inhibition performance of the hybrid gel on coal spontaneous combustion indicates that the addition of the gel slows down the oxygen chemisorption and thus increases the ignition temperature. Due to the presence of the hybrid gel in the coal, the crossing point temperatures were increased and the lowest CO concentration was produced.

Topics & Concepts

BentoniteMaterials scienceChemical engineeringXanthan gumSilica gelCompressive strengthAutoignition temperatureComposite materialAdsorptionPolyvinyl alcoholCombustionRheologyChemistryOrganic chemistryEngineeringFlame retardant materials and propertiesCoal Properties and UtilizationFire dynamics and safety research