Effective C<sub>2</sub>H<sub>2</sub> Separation and Nitrofurazone Detection in a Stable Indium–Organic Framework
Qianqian Chu, Bin Zhang, Hui-Fang Zhou, Bo Liu, Lei Hou, Yao‐Yu Wang
Abstract
Based on the mixed carboxylate ligands synthesis strategy, an indium–organic framework, (Me2NH2)1.5[In1.5(FBDC)(BDC)]·2.5NMF·CH3CN (1) has been constructed by using the mixed (2,5-di(2′,5′-dicarboxylphenyl)-difluorobenzene (H4FBDC) and terephthalic acid (H2BDC). Compound 1 contains a 3D intersecting pore system which surface is modified by F atoms, and it has excellent stability in pH = 2−12 aqueous solutions. The activated 1 shows high separation for C2H2/CO2 and C2H2/CH4. Moreover, 1 not only has strong luminescence but also has the high selectivity and sensibility of fluorescence detection to nitrofurazone (NZF) in antibiotic sensing experiments, which can be used as a luminescence sensor for NZF detection.