Pd(<scp>ii</scp>)-catalyzed β- and γ-C-(sp<sup>3</sup>)–H dienylation with allenyl acetates
Rahul K. Shukla, Akshay M. Nair, Chandra M. R. Volla
Abstract
A Pd( ii )-catalyzed highly regioselective dienylation of sp 3 C–H bonds has been accomplished engaging allenes for a variety of aliphatic carboxamides including fatty acids and amino acids.
Topics & Concepts
CatalysisChemistryMedicinal chemistryStereochemistryCombinatorial chemistryOrganic chemistryCatalytic C–H Functionalization MethodsCatalytic Alkyne ReactionsSynthesis and Catalytic Reactions